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Which is the most reasonable prediction for the H-N-H bond angle in NH3?


A) 90°
B) 109.5°
C) 120°
D) 107°
E) 105°

F) C) and D)
G) B) and D)

Correct Answer

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What is the hybridization on the central atom in NO3- ?


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and C)
G) None of the above

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What is the molecular geometry of N2O as predicted by the VSEPR model? What is the molecular geometry of N<sub>2</sub>O as predicted by the VSEPR model?   A) trigonal pyramidal B) trigonal planar C) tetrahedral D) bent E) linear


A) trigonal pyramidal
B) trigonal planar
C) tetrahedral
D) bent
E) linear

F) B) and D)
G) B) and E)

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Which is true concerning the dipole moment of a CO2 molecule?


A) The dipole moment is zero because the C-O bond is nonpolar.
B) The dipole moment is zero because the molecule is linear.
C) The dipole moment is zero because the molecule is bent.
D) The dipole moment is nonzero because the molecule is linear.
E) The dipole moment is nonzero because the molecule is bent.

F) A) and B)
G) A) and D)

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Rank the following molecules in order of increasing dipole moment. Rank the following molecules in order of increasing dipole moment.   A) III < II < I B) III < I < II C) I < II < III D) I < III < II E) II < III < I


A) III < II < I
B) III < I < II
C) I < II < III
D) I < III < II
E) II < III < I

F) A) and B)
G) All of the above

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What is the molecular geometry of the thiocyanate anion,SCN-,as predicted by the VSEPR model? (Carbon is the central atom.)


A) linear
B) bent
C) tetrahedral
D) trigonal planar
E) trigonal pyramidal

F) A) and C)
G) D) and E)

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Which one of the following molecules is polar?


A) PBr5
B) CCl4
C) BrF5
D) XeF2
E) XeF4

F) All of the above
G) A) and D)

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Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide,SO2 .


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) None of the above
G) B) and C)

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According to molecular orbital theory,what is the bond order in the O2- ion?


A) 5.5
B) 5
C) 4
D) 2.5
E) 1.5

F) None of the above
G) C) and E)

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E

Hyposulfite,SO22-,is a polyatomic ion that has not yet been definitively confirmed to exist.However,the VSEPR model may still be applied to yield a prediction on its molecular geometry.What is the most reasonable estimate for the O-S-O bond angle in hyposulfite?


A) 90°
B) 106°
C) 109.5°
D) 112°
E) 120°

F) C) and D)
G) A) and B)

Correct Answer

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What is the hybridization of the As atom in the AsF5 molecule?


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) A) and E)

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According to the VSEPR model,the predicted molecular geometry of the SO3 molecule is


A) pyramidal.
B) tetrahedral.
C) trigonal planar.
D) seesaw.
E) square planar.

F) C) and E)
G) A) and E)

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Water has ___________ (number)lone pair(s)of electrons on the central oxygen.

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Using the VSEPR model,predict the molecular geometry around the central atom in PO43-.


A) trigonal planar
B) trigonal pyramidal
C) tetrahedral
D) trigonal bipyramidal
E) octahedral

F) All of the above
G) B) and D)

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According to the VSEPR model,a molecule with the general formula AB5 with one lone pair on the central atom will have a ______ molecular geometry.


A) tetrahedral
B) trigonalbipyramidal
C) square pyramidal
D) octahedral
E) seesaw

F) A) and E)
G) All of the above

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C

Allene,C3H4 (shown below) ,is one component of gas used for high-temperature welding. According to the valence bond model,which is a proper description of the bonding on the central carbon atom in allene? Allene,C<sub>3</sub>H<sub>4</sub> (shown below) ,is one component of gas used for high-temperature welding. According to the valence bond model,which is a proper description of the bonding on the central carbon atom in allene?   A) It shares four π bonds,two with each carbon atom on either side. B) It shares four σ bonds,two with each carbon atom on either side. C) It shares one σ bond and one π bond with each carbon atom on either side. D) It shares two σ bonds with the carbon atom on the left,and two π bonds with the carbon atom on the right. E) It shares two σ bonds with the carbon atom on the right,and two π bonds with the carbon atom on the left.


A) It shares four π bonds,two with each carbon atom on either side.
B) It shares four σ bonds,two with each carbon atom on either side.
C) It shares one σ bond and one π bond with each carbon atom on either side.
D) It shares two σ bonds with the carbon atom on the left,and two π bonds with the carbon atom on the right.
E) It shares two σ bonds with the carbon atom on the right,and two π bonds with the carbon atom on the left.

F) A) and C)
G) B) and C)

Correct Answer

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Thiocarbonyl disulfide (CSF2) ,based on the coordinate axes provided below,in which direction does the net molecular dipole moment point for the molecule? Thiocarbonyl disulfide (CSF<sub>2</sub>) ,based on the coordinate axes provided below,in which direction does the net molecular dipole moment point for the molecule?   A) It points in the +x direction. B) It points in the -x direction. C) It points in the +y direction. D) It points in the -y direction. E) The molecule does not have a net molecular dipole moment.


A) It points in the +x direction.
B) It points in the -x direction.
C) It points in the +y direction.
D) It points in the -y direction.
E) The molecule does not have a net molecular dipole moment.

F) All of the above
G) C) and D)

Correct Answer

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What is the molecular geometry of ClF2- as predicted by the VSEPR model?


A) linear
B) bent
C) seesaw
D) T-shaped
E) trigonal bipyramidal

F) A) and B)
G) A) and E)

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Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)


A) Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)  A)    B)    C)    D)    E)
B) Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)  A)    B)    C)    D)    E)
C) Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)  A)    B)    C)    D)    E)
D) Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)  A)    B)    C)    D)    E)
E) Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the models,if any,are not shown.)  A)    B)    C)    D)    E)

F) A) and C)
G) C) and D)

Correct Answer

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A

The BrF5 molecule has polar bonds and has a net dipole moment.

A) True
B) False

Correct Answer

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