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The triple point of iodine is at 0.12 atm and 115°C.Thus,liquid I2


A) is more dense than I2(s) .
B) cannot exist above 115°C.
C) is liquid at room temperature.
D) cannot have a vapor pressure less than 91 torr.
E) sublimes at high pressure.

F) A) and D)
G) A) and C)

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Which of the following is defined as the attractive forces between polar molecules? I.dispersion forces II) dipole-dipole interactions III) ion-dipole interactions


A) I and III
B) II only
C) III only
D) I,II,and III
E) I only

F) B) and E)
G) A) and E)

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B

Which corresponds to the temperature-dependent partial pressure above the surface of a liquid?


A) Surface tension
B) Vapor pressure
C) Boiling point
D) Viscosity
E) Capillary action

F) A) and B)
G) None of the above

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Which substance will exhibit hydrogen bonding between molecules?


A) (CH3) 3N
B) CH3-O-CH3
C) CH3CH2-OH
D) CH3CH2-F
E) HI

F) All of the above
G) C) and E)

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a.Name the two unit cells which occur in close packing of identical atoms. b.Briefly explain how the two types of close-packed lattices of identical atoms differ,in terms of atomic arrangements.

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a.face-centered cubic; hexagonal b.Cubic...

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The location that indicates conditions under which two phases can exist in equilibrium is called the


A) triple point.
B) critical point.
C) phase boundary.
D) phase diagram.
E) transition state.

F) A) and C)
G) A) and B)

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Palladium crystallizes in a face-centered cubic unit cell.Its density is 12.0 g/cm3 at 27°C.What is the atomic radius of Pd?


A) 138 pm
B) 1.95 × 10-8 nm
C) 1.95 × 10-8 cm
D) 154 pm
E) 0.109 nm

F) C) and D)
G) C) and E)

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Crystals of elemental sulfur are easily crushed,and melt at 113°C.Liquid sulfur does not conduct electricity.What kind of crystal is this?

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Arrange the following in order of increasing boiling point: RbCl,CH3Cl,CH3OH,CH4.


A) CH3OH < CH3Cl < RbCl < CH4
B) CH3OH < CH4 < CH3Cl < RbCl
C) RbCl < CH3 Cl < CH3 OH < CH4
D) CH4 < CH3OH < CH3Cl < RbCl
E) CH4 < CH3Cl < CH3OH < RbCl

F) B) and D)
G) A) and E)

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Ammonia's unusually high melting point is the result of


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) ionic bonding.

F) A) and D)
G) None of the above

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________________ _________ are the attractions that hold particles together in condensed phases.

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Intermolec...

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The molar enthalpy of vaporization of hexane (C6H14) is 28.9 kJ/mol,and its normal boiling point is 68.73°C.What is the vapor pressure of hexane at 25°C? (R = 8.314 J/K • mol)


A) 171 torr
B) 4.44 torr
C) 117 torr
D) 3370 torr
E) 759 torr

F) B) and C)
G) A) and E)

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What name is given to a quantitative measure of the elastic force in the surface of a liquid?


A) Surface tension
B) Adhesion
C) Polarity
D) Capillary action
E) Cohesion

F) A) and E)
G) A) and B)

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What name is given to the phenomenon where a thin film of water contracts and adheres to the wall of a glass cylinder?


A) Surface tension
B) Adhesion
C) Polarity
D) Capillary action
E) Cohesion

F) C) and D)
G) A) and D)

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D

The energy of a hydrogen bond is greater than that of a typical covalent bond.

A) True
B) False

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Which statement concerning the vapor pressures of water and methanol (CH3OH) is true?


A) At 25ºC,methanol has a higher vapor pressure than water because methanol has a lower normal boiling point than water.
B) At 25ºC,methanol has a higher vapor pressure than water because methanol is a poorer solvent than water.
C) At 25ºC,methanol has a higher vapor pressure than water because methanol is a less viscous liquid than water.
D) At 25ºC,methanol has a higher vapor pressure than water because the density of methanol is less than the density of water.
E) At 25ºC,methanol has a higher vapor pressure than water because methanol has weaker intermolecular forces than water.

F) A) and D)
G) A) and E)

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E

What is the name given to the attractive forces that hold particles together in the condensed phase?


A) ionic bonds
B) covalent bonds
C) intermolecular forces
D) electronegativity
E) electron attraction

F) A) and B)
G) C) and D)

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The zincblende structure of ZnS has the relatively large sulfide ions arranged at the lattice points of a face-centered cubic structure.The edge length of this cubic unit cell is 540.9 pm.Determine the density of zincblende.


A) 0.244 g/cm3
B) 1.02 g/cm3
C) 2.05 g/cm3
D) 4.09 g/cm3
E) 8.18 g/cm3

F) A) and B)
G) A) and C)

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Which are considered van der Waals forces? I.dispersion forces II) dipole-dipole interactions III) hydrogen bonding


A) I and III
B) II only
C) III only
D) I,II,and III
E) I only

F) B) and E)
G) B) and D)

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Lead crystallizes in the face-centered cubic lattice.What is the coordination number for Pb?


A) 4
B) 6
C) 8
D) 10
E) 12

F) B) and C)
G) C) and D)

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