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What is the pH of a buffer that consists of 0.20 M Na H2PO4 and 0.40 M Na2HPO4? [Ka(Na H2PO4) = 6.2 × 10-8]


A) 6.51
B) 6.91
C) 7.51
D) 7.90
E) 8.13

F) A) and C)
G) A) and B)

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What is the effect on equilibrium when sodium acetate is added to a solution of acetic acid? CH3COOH(aq) What is the effect on equilibrium when sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)    H<sup>+</sup>(aq) + CH<sub>3</sub>COO<sup>-</sup>(aq)  A) There is no change in the equilibrium. B) The equilibrium shifts to the right. C) More information is needed to answer the question. D) The equilibrium shifts to the left. E) The pH decreases. H+(aq) + CH3COO-(aq)


A) There is no change in the equilibrium.
B) The equilibrium shifts to the right.
C) More information is needed to answer the question.
D) The equilibrium shifts to the left.
E) The pH decreases.

F) All of the above
G) B) and D)

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The ___________________ is the point in a titration where neutralization is complete.

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Does a precipitate of magnesium fluoride form if 300.0 mL of 1.1 × 10-3 M MgCl2 are added to 500.0 mL of 1.2 × 10-3 M NaF? [Ksp (MgF2) = 6.9 × 10-9]


A) Yes,because Q > Ksp.
B) No,because Q < Ksp.
C) No,because Q = Ksp.
D) Yes,because Q < Ksp.
E) No,because Q > Ksp.

F) D) and E)
G) A) and C)

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A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH.The following data were collected during the titration.Determine to Ka for HClO. mL NaOH added 5) 00 10) 00 15) 00 20) 00 PH 6) 98 7) 46 7) 93 10) 31


A) 1.1 × 10-7
B) 3.5 × 10-8
C) 1.2 × 10-8
D) 4.9 × 10-11
E) None of the answers is correct.

F) A) and B)
G) C) and E)

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Bromothymol blue is a common acid-base indicator.It has a Ka equal to 1.6 × 10-7.Its un-ionized form is yellow and its conjugate base is blue.What color would a solution have at pH = 5.8?

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Which of the following compounds is appreciably more soluble in 1 M HNO3 than in pure water?


A) FeCO3
B) AgBr
C) BaSO4
D) NaNO3
E) NaCl

F) A) and B)
G) B) and E)

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A 20.00-mL sample of 0.3000 M HBr is titrated with 0.15 M NaOH.What is the pH of the solution after 40.3 mL of NaOH have been added to the acid?


A) 1.00
B) 3.13
C) 10.87
D) 11.05
E) 13.14

F) C) and E)
G) A) and D)

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The endpoint in a titration is defined as the point when the appropriate indicator changes color.

A) True
B) False

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When the concentration of the conjugate base of a weak acid is less than the concentration of the weak acid in a buffer solution,the pH of the solution is


A) less than the pKa.
B) greater than the pKa.
C) always acidic.
D) always basic.
E) equal to the pKa.

F) B) and C)
G) C) and D)

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H) and 0.15 M sodium benzoate (C6H5COONa) .(Ka = 6.5 × 10-5 for benzoic acid)


A) 3.97
B) 4.83
C) 4.19
D) 3.40
E) 4.41

F) A) and B)
G) C) and E)

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Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH. Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH.   What is the approximate pK<sub>a</sub> of HA? A) 4 B) 6 C) 8 D) 9 E) 12 What is the approximate pKa of HA?


A) 4
B) 6
C) 8
D) 9
E) 12

F) A) and B)
G) A) and C)

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Which best describes the pH at the equivalence point of a titration of a weak acid with a strong base?


A) Less than zero
B) Between 0 and 7
C) Close to 7.0
D) Between 7 and 14
E) Greater than 14

F) C) and E)
G) None of the above

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_______________ is the way to identify the types of ions in a solution using selective precipitation.

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Consider the dissolution of MnS in water.[Ksp(MnS) =3.0 × 10-14] MnS(s) + H2O(l) Consider the dissolution of MnS in water.[K<sub>sp</sub>(MnS) =3.0 × 10<sup>-14</sup>] MnS(s) + H<sub>2</sub>O(l)    Mn<sup>2+</sup>(aq) + HS<sup>-</sup>(aq) + OH<sup>-</sup>(aq)  How is the solubility of manganese(II) sulfide affected by the addition of aqueous potassium hydroxide to the system? A) The solubility will be unchanged. B) The solubility will decrease. C) The solubility will increase. D) The amount of KOH added must be known before its effect can be predicted. E) The pK<sub>a</sub> of H<sub>2</sub>S is needed before a reliable prediction can be made. Mn2+(aq) + HS-(aq) + OH-(aq) How is the solubility of manganese(II) sulfide affected by the addition of aqueous potassium hydroxide to the system?


A) The solubility will be unchanged.
B) The solubility will decrease.
C) The solubility will increase.
D) The amount of KOH added must be known before its effect can be predicted.
E) The pKa of H2S is needed before a reliable prediction can be made.

F) A) and E)
G) B) and C)

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Calculate the NaOH concentration necessary to precipitate Ca(OH) 2 from a solution in which [Ca2+] = 1.0.Ksp of Ca(OH) 2 = 8 x 10-6.


A) 6.7 x 10-8 M
B) 2.8 x 10-3 M
C) 1.5 x 10-7 M
D) 0.10 M

E) B) and D)
F) C) and D)

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A buffer is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH.What is the pH of this buffer? [Ka(CH3COOH) = 1.8 × 10-5]


A) 4.57
B) 4.52
C) 4.87
D) 4.92
E) 4.97

F) B) and D)
G) D) and E)

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An acetic acid buffer containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74.What will the pH be after 0.0020 mol of HCl has been added to 100.0 mL of the buffer?


A) 4.77
B) 4.71
C) 4.68
D) 4.62
E) 1.70.

F) B) and D)
G) A) and E)

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The __________ is the solution that is added from the buret during a titration.

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Which is more soluble in a basic solution than in pure water?


A) Mg(OH) 2
B) CaHPO4
C) NaCl
D) CaCO3
E) AgI

F) A) and B)
G) A) and C)

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