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What product forms at the cathode during the electrolysis of molten lithium iodide?


A) Li+(l)
B) Li(l)
C) I-(l)
D) I2(g)
E) I3-(l)

F) B) and E)
G) None of the above

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What is ΔG° at 298 K for the following reaction? (F = 96,500 C • mol -1) What is ΔG° at 298 K for the following reaction? (F = 96,500 C • mol<sup> -1</sup>)    A)  -921 kJ/mol B)  -767 kJ/mol C)  -460 kJ/mol D)  -307 kJ/mol E)  -1840 kJ/mol


A) -921 kJ/mol
B) -767 kJ/mol
C) -460 kJ/mol
D) -307 kJ/mol
E) -1840 kJ/mol

F) C) and D)
G) A) and E)

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Reduction occurs at the anode of a galvanic cell.

A) True
B) False

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When the following redox equation is balanced with the smallest whole number coefficients, what is the coefficient of Zn(s) ? Zn(s) + ReO4-(aq) → Re(s) + Zn2+(aq) (acidic solution)


A) 2
B) 7
C) 8
D) 16
E) None of these choices is correct.

F) D) and E)
G) C) and D)

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Consider the following redox equation. Mn(OH) 2(s) + MnO4-(aq) → MnO42-(aq) (basic solution) When the equation is balanced with the smallest whole number coefficients, what is the coefficient for OH-(aq) and on which side of the equation is OH-(aq) present?


A) 4, reactant side
B) 4, product side
C) 6, reactant side
D) 6, product side
E) 8, reactant side

F) C) and E)
G) B) and D)

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What is the cell potential at 25°C for the following reaction if [Zn2+] = 1.0 × 10-4 M and [Sn2+] = 0.20 M ? (R = 8.314 J/K • mol, F = 96,500 C • mol -1) What is the cell potential at 25°C for the following reaction if [Zn<sup>2+</sup>] = 1.0 × 10<sup>-4 </sup><sup>M</sup> and [Sn<sup>2+</sup>] = 0.20 M ? (R = 8.314 J/K • mol, F = 96,500 C • mol<sup> -1</sup>)    A)  -0.62 V B)  +0.52 V C)  -0.52 V D)  -0.72 V E)  +0.72 V


A) -0.62 V
B) +0.52 V
C) -0.52 V
D) -0.72 V
E) +0.72 V

F) A) and C)
G) D) and E)

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What mass of nickel may be electroplated by passing a constant current of 7.2 A through a solution of NiSO4 for 90.0 min?


A) 0.20 g Ni
B) 0.40 g Ni
C) 12 g Ni
D) 24 g Ni
E) 47 g Ni

F) A) and E)
G) A) and C)

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Lithium-ion batteries can be recharged many times.

A) True
B) False

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For E° and ΔG° the zero (superscript) represents the standard state. What is the standard state?

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For gases, partial p...

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If E° for X + e- → Y is larger than E° for A + 2e- → B, then in a spontaneous process under standard-state conditions,


A) X will oxidize A.
B) Y will oxidize A.
C) Y will reduce A.
D) B will oxidize X.
E) B will reduce X.

F) A) and B)
G) B) and D)

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Based on the data presented below, which is the strongest oxidizing agent? Based on the data presented below, which is the strongest oxidizing agent?   A)  Fe<sup>3+</sup> B)  Fe<sup>2+</sup> C)  Br<sup>-</sup> D)  Al<sup>3+</sup> E)  Al(s)


A) Fe3+
B) Fe2+
C) Br-
D) Al3+
E) Al(s)

F) C) and D)
G) C) and E)

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A voltaic cell consists of a Hg/Hg22+ electrode (E°= 0.85 V) and a Sn/Sn2+ electrode (E°= -0.14 V) . Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25°C.


A) 0.00010 M
B) 0.00070 M
C) 0.0049 M
D) 0.030 M
E) 0.050 M

F) A) and D)
G) D) and E)

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Given Cu2+(aq) + 2e- → Cu(s) E° = +0.34 V Al3+(aq) + 3e- → Al(s) E° = -1.66 V Na+(aq) + e- → Na(s) E° = -2.71 V Which of the following reactions will occur?


A) 2Na+(aq) + Cu(s) → Cu2+(aq) + 2Na(s)
B) Al(s) + 3Na+(aq) → Al3+(aq) + 3Na(s)
C) 2Na(s) + Cu2+(aq) → Cu(s) + 2Na+(aq)
D) 2Al3+(aq) + 3Cu(s) → 3Cu2+(aq) + 2Al(s)
E) None of these will occur.

F) A) and B)
G) A) and E)

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If the following electrochemical cell is constructed, what voltage will be measured on the voltmeter? If the following electrochemical cell is constructed, what voltage will be measured on the voltmeter?     A)  2.36 V B)  1.56 V C)  0.04 V D)  -0.04 V E)  -2.36 V If the following electrochemical cell is constructed, what voltage will be measured on the voltmeter?     A)  2.36 V B)  1.56 V C)  0.04 V D)  -0.04 V E)  -2.36 V


A) 2.36 V
B) 1.56 V
C) 0.04 V
D) -0.04 V
E) -2.36 V

F) A) and C)
G) A) and B)

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What is E°cell for the following reaction, and is it spontaneous or nonspontaneous under standard-state conditions? 2Fe3+(aq) + 2H2O(l) → H2O2(aq) + 2H+(aq) + 2Fe2+(aq) Given: What is E°<sub>cell</sub> for the following reaction, and is it spontaneous or nonspontaneous under standard-state conditions? 2Fe<sup>3+</sup>(aq)  + 2H<sub>2</sub>O(l)  → H<sub>2</sub>O<sub>2</sub>(aq)  + 2H<sup>+</sup>(aq)  + 2Fe<sup>2+</sup>(aq)  Given:   A)  E°<sub>cell</sub> = -1.00 V, nonspontaneous B)  E°<sub>cell</sub> = -1.00 V, spontaneous C)  E°<sub>cell</sub> = 1.00 V, nonspontaneous D)  E°<sub>cell</sub> = 1.00 V, spontaneous E)  E°<sub>cell</sub> = -0.23 V, nonspontaneous


A) E°cell = -1.00 V, nonspontaneous
B) E°cell = -1.00 V, spontaneous
C) E°cell = 1.00 V, nonspontaneous
D) E°cell = 1.00 V, spontaneous
E) E°cell = -0.23 V, nonspontaneous

F) A) and B)
G) B) and C)

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Which component of the following cell is the cathode? K|L||M|N


A) K
B) L
C) M
D) N

E) B) and D)
F) A) and B)

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Iron objects such as storage tanks and underground pipelines can be protected from corrosion by connecting them through a wire to a piece of


A) Pb.
B) Ag.
C) Sn.
D) Mg.
E) Cu.

F) None of the above
G) C) and D)

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A voltaic cell consists of an Au/Au3+ electrode (E° = 1.50 V) and a Cu/Cu2+ electrode (E° = 0.34 V) . Calculate [Au3+] if [Cu2+] = 1.20 M and Ecell = 1.15 V at 25°C.


A) 0.0010 M
B) 0.0020 M
C) 0.010 M
D) 0.020 M
E) 0.41 M

F) A) and C)
G) A) and D)

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A voltaic cell is prepared using copper and silver. Its cell notation is shown below. Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s) Which reaction occurs at the cathode?


A) Cu(s) → Cu2+(aq) + 2e-
B) Cu2+(aq) + 2e- → Cu(s)
C) Ag(s) → Ag+(aq) + e-
D) Ag+(aq) + e- → Ag(s)
E) Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)

F) C) and E)
G) B) and E)

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Which of the following is correct?


A) total charge = volts/coulombs
B) electrical energy = volts × coulombs
C) Faraday = coulombs/joules
D) coulombs = joules × volts
E) electrical work = Faraday's constant/Ecell

F) None of the above
G) C) and D)

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