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Which of the following geometries is not common in transition-metal complex ions?


A) Tetrahedral
B) Octahedral
C) Linear
D) Trigonal planar
E) Square planar

F) A) and B)
G) A) and C)

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What is the difference between a coordination compound and a complex ion?

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A coordination compound genera...

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In the complex ion [Fe(CN) 6]4-, what is the oxidation number of Fe?


A) +1
B) +2
C) +3
D) -4
E) +6

F) All of the above
G) A) and B)

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In the spectrochemical series, which one of the following ligands has the strongest field?


A) H2O
B) CN-
C) NH3
D) OH-
E) Cl-

F) C) and E)
G) C) and D)

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Which of the following metals is capable of forming complexes spanning the smallest range of oxidation numbers?


A) Cu
B) Sc
C) Fe
D) Mn
E) Ni

F) C) and D)
G) A) and E)

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In a reaction between a metal ion and a group of anions or a polar molecule, the anions or polar molecule acts as a ________ ________.

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Why is the +2 oxidation state so common among transition elements?

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The outermost electr...

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How many 3d electrons does a ground-state Nb3+ ion have?


A) 2
B) 4
C) 3
D) 10
E) 5

F) A) and E)
G) B) and C)

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What is the name of the molecules or ions that surround the metal in a complex ion?


A) Chelaters
B) Donors
C) Acceptors
D) Coordinators
E) Ligands

F) C) and E)
G) A) and D)

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The compound Rh(CO)(H)(PH3)2 forms cis and trans isomers. Use this information to predict the geometry of this complex isomer.

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The complex has four ligands a...

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How many 3d electrons does a ground-state Pd2+ ion have?


A) 8
B) 10
C) 9
D) 7
E) 6

F) B) and C)
G) C) and D)

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What is the electron configuration of a ground-state Cu+ ion?


A) [Ar]3d10
B) [Ar]4d10
C) [Ar]3d9
D) [Ar]4d9
E) None of these choices.

F) B) and E)
G) A) and E)

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What is the coordination number of cobalt in the complex ion [Co(en) Cl4]-? (en = ethylenediamine)


A) 1
B) 2
C) 4
D) 6
E) 8

F) A) and E)
G) B) and C)

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Which of the following metals is capable of forming complexes spanning the largest range of oxidation numbers?


A) Cu
B) Sc
C) Fe
D) Mn
E) Ni

F) A) and B)
G) A) and E)

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Cisplatin complexes are


A) used in the extraction of silver and gold.
B) effective antidotes for heavy metal poisoning (e.g., Pb2+ and Hg2+) .
C) used to provide nutrients for plants.
D) used to prevent eutrophication of lakes.
E) effective antitumor agents.

F) D) and E)
G) None of the above

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Ethylenediaminetetraacetic acid (EDTA) is


A) not useful as a chelating agent.
B) an effective antidote for heavy metal poisoning (e.g., Pb2+ and Hg2+) .
C) a monodentate ligand.
D) known to form unstable complex ions with Fe3+, Hg2+, and Zn2+.
E) known to form complexes with platinum that inhibit the growth of cancerous cells.

F) B) and E)
G) All of the above

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Which of the following ligands is most likely to form a high-spin octahedral complex with cobalt(II) ?


A) CN-
B) en (ethylenediamine)
C) NH3
D) CO
E) I-

F) A) and E)
G) C) and D)

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What is the electron configuration of a ground-state Zn2+ ion?


A) 1s22s22p63s23p64s13d9
B) 1s22s22p63s23p64s14d9
C) 1s22s22p63s23p64s23d8
D) 1s22s22p63s23p64s24d8
E) 1s22s22p63s23p63d10

F) B) and C)
G) A) and B)

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Which statement is correct about coordination compounds?


A) They consist only of nonmetals.
B) They contain ionic bonds.
C) They are formed by reactions of metal ions with groups of anions or polar molecules.
D) They contain only metals.

E) A) and B)
F) A) and C)

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Which of the following ions is paramagnetic?


A) Sc3+
B) Ti4+
C) Mn7+
D) Ni2+
E) V5+

F) B) and D)
G) A) and D)

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