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The Henry's Law constant (k) for carbon monoxide in water at 25°C is 9.71 × 104 mol/(L·atm) . How many grams of CO will dissolve in 1.00 L of water if the partial pressure of CO is 2.75 atm?


A) 3.53 × 10 4 g
B) 2.67 × 10 3 g
C) 9.89 × 10 3 g
D) 7.48 × 10 2 g
E) None of these choices are correct.

F) A) and E)
G) C) and D)

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The vapor pressure of pure acetone (propanone) is 266 torr. When a non-volatile solute is added, the vapor pressure of acetone above the solution falls to 232 torr. What is the mole fraction of the non-volatile solute in the solution?


A) 0.87
B) 0.69
C) 0.32
D) 0.13
E) 0.045

F) B) and D)
G) A) and B)

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Safrole is used as a topical antiseptic. Calculate the vapor pressure of a solution prepared by dissolving 0.75 mol of safrole in 950 g of ethanol (ℳ = 46.07 g/mol) . P°ethanol = 50.0 torr at 25°C.


A) 1.8 torr
B) 11 torr
C) 15 torr
D) 40 torr
E) 48 torr

F) A) and B)
G) C) and E)

Correct Answer

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Calculate the molarity of a solution prepared by diluting 1.85 L of 6.5 M KOH to 11.0 L.


A) 0.28 M
B) 0.91 M
C) 1.1 M
D) 3.1 M
E) 3.9 M

F) A) and E)
G) B) and D)

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Procaine hydrochloride (ℳ = 272.77 g/mol) is used as a local anesthetic. Calculate the molarity of a 4.666 m solution which has a density of 1.1066 g/mL.


A) 2.272 M
B) 4.056 M
C) 4.216 M
D) 4.666 M
E) None of these choices are correct.

F) A) and C)
G) None of the above

Correct Answer

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A solution of ethanol (C2H6O) in water is sometimes used as a disinfectant. 1.00 L of this solution contains 553 g of ethanol and 335 g of water. What is the mole fraction of ethanol in this solution?


A) 0.377
B) 0.392
C) 0.553
D) 0.608
E) 0.623

F) A) and B)
G) D) and E)

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The solubility of gases in water increases with increase in the pressure of the gas.

A) True
B) False

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Determine the freezing point of a solution that contains 0.31 mol of sucrose in 175 g of water. Kf = 1.86°C/m


A) 3.3°C
B) 1.1°C
C) 0.0°C
D) −1.1°C
E) −3.3°C

F) A) and E)
G) A) and B)

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Heats of solution may be either positive or negative.

A) True
B) False

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Copper(II) bromide is used as a wood preservative. What mass of CuBr2 is needed to prepare 750.0 mL of a 1.25 M solution?


A) 134 g
B) 209 g
C) 372 g
D) 938 g
E) > 1 kg

F) A) and B)
G) A) and D)

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What is the molality of a solution prepared by dissolving 86.9 g of diethyl ether, C4H10O, in 425 g of benzene, C6H6?


A) 0.362 m
B) 0.498 m
C) 2.01 m
D) 2.76 m
E) None of these choices are correct.

F) D) and E)
G) A) and C)

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Benzaldehyde ( ℳ = 106.1 g/mol) , also known as oil of almonds, is used in the manufacture of dyes and perfumes and in flavorings. What would be the freezing point of a solution prepared by dissolving 75.00 g of benzaldehyde in 850.0 g of ethanol?Kf = 1.99°C/m, freezing point of pure ethanol = -117.3°C.


A) −117.5°C
B) −118.7°C
C) −119.0°C
D) −120.6°C
E) < −121°C

F) None of the above
G) B) and E)

Correct Answer

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Cadmium bromide is used in photography and lithography. Calculate the molality of a solution prepared by dissolving 45.38 g of CdBr2 in 375.0 g of water.


A) 0.03035 m
B) 0.01600 m
C) 0.1210 m
D) 0.4446 m
E) None of these choices are correct.

F) B) and C)
G) A) and C)

Correct Answer

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Colloidal particles may be solids, liquids, or gases.

A) True
B) False

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The shape of a protein molecule is determined completely by


A) hydrogen bonding.
B) ion-dipole attractions.
C) dispersion forces.
D) disulfide bridges.
E) the sequence of amino acids in the chain.

F) All of the above
G) A) and E)

Correct Answer

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The vapor pressure of pure acetone (propanone) is 266 torr. When a non-volatile solute is added, the vapor pressure of acetone above the solution falls to 232 torr. What is the mole fraction of acetone in the solution?


A) 0.87
B) 0.69
C) 0.32
D) 0.13
E) 0.045

F) A) and E)
G) A) and B)

Correct Answer

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A solution of sucrose (sugar) in water is in equilibrium with solid sucrose. If more solid sucrose is now added, with stirring,


A) the concentration of the solution will increase.
B) the concentration of the solution will decrease.
C) the concentration of the solution will remain the same.
D) the volume of solution will increase.
E) a supersaturated solution will be produced.

F) A) and D)
G) C) and E)

Correct Answer

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From the following list of aqueous solutions and water, select the one with the highest boiling point.


A) 1.0 m KNO 3
B) 0.75 m NaCl
C) 0.75 m CuCl 2
D) 2.0 m C 12H 22O 11 (sucrose)
E) pure water

F) C) and E)
G) B) and D)

Correct Answer

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In general, water is a good solvent for both polar and nonpolar compounds.

A) True
B) False

Correct Answer

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The most abundant molecules in the cell membranes of most species are


A) proteins.
B) sugars.
C) phospholipids.
D) fatty acids.
E) steroids.

F) B) and C)
G) All of the above

Correct Answer

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