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Which one of the following statements about atomic structure and quantum numbers is incorrect?


A) In a given atom, the maximum number of electrons having principal quantum number n = 3, is 18.
B) The number of orbitals in a given f subshell is 7.
C) For n = 4, the largest possible value of l is 3.
D) For n = 4, the largest possible value of ml is 2.
E) The following set of quantum numbers for a single orbital is not allowed: n = 3, l = 1, ml = −2.

F) None of the above
G) B) and C)

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Select the element with the greatest metallic character.


A) Li
B) Ca
C) Al
D) Pb
E) Cs

F) A) and B)
G) A) and C)

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of potassium, K.


A) 4, 1, −1, ½
B) 4, 1, 0, ½
C) 4, 0, 1, ½
D) 4, 0, 0, ½
E) 4, 1, 1, ½

F) A) and B)
G) A) and D)

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Select the diamagnetic ion.


A) Cu 2+
B) Ni 2+
C) Cr 3+
D) Sc 3+
E) Cr 2+

F) A) and B)
G) A) and C)

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In forming ions of the first series of transition metals, the 4s electrons are lost before the 3d electrons.

A) True
B) False

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How many valence electrons are there in an atom with the electron configuration [noble gas]ns2(n − 1) d8?


A) 2
B) 6
C) 8
D) 10
E) None of these choices are correct.

F) A) and E)
G) A) and D)

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Consider the set of isoelectronic atoms and ions A2, B, C, D+, and E2+. Which arrangement of relative radii is correct?


A) A 2 > B > C > D + > E 2+
B) E 2+ > D + > C > B > A 2
C) A 2 > B > C < D + < E 2+
D) A 2 < B < C > D + > E 2+
E) None of these choices are correct.

F) None of the above
G) B) and C)

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Elements with the highest first ionization energies are found in the __________ region of the periodic table.


A) lower left
B) upper left
C) center
D) lower right
E) upper right

F) C) and D)
G) A) and D)

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Which of the following elements will form a cation with a +2 charge?


A) Si
B) Sr
C) Ga
D) Cs
E) S

F) C) and D)
G) B) and D)

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Select the correct electron configuration for Cu (Z = 29) .


A) [Ar]4 s 23 d 9
B) [Ar]4 s 13 d 10
C) [Ar]4 s 24 p 63 d 3
D) [Ar]4 s 24 d 9
E) [Ar]5 s 24 d 9

F) None of the above
G) B) and C)

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Which one of the following equations correctly represents the process relating to the ionization energy of X?


A) X( s) → X +( g) + e
B) X 2( g) → X +( g) + X ( g)
C) X( g) + e → X ( g)
D) X ( g) → X( g) + e
E) X( g) → X +( g) + e

F) A) and C)
G) None of the above

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of tin, Sn.


A) 5, 2, −1, ½
B) 5, 2, 0, ½
C) 5, 1, 2, ½
D) 5, 1, 0, ½
E) 5, 2, 1, ½

F) B) and E)
G) None of the above

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Elements in the same period of the periodic table have similar valence shell electron configurations.

A) True
B) False

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Which of the following electron configurations represents the ground state of an element?


A) [Ne]3 s 13 p 1
B) [He]2 s 12 p 3
C) [Ne]3 s 23 p 23 d 1
D) [Ne]3 s 23 p 33 d 1
E) [Ne]3 s 23 p 3

F) All of the above
G) A) and B)

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Identify the element of Period 2 which has the following successive ionization energies,in kJ/mol. IE1, 1314 IE2, 3389 IE3, 5298 IE4, 7471 IE5, 10992 IE6, 13329 IE7, 71345 IE8, 84087


A) Li
B) B
C) O
D) Ne
E) None of these choices are correct.

F) A) and B)
G) C) and D)

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Select the element with the most negative electron affinity (i.e., accepts an electron most readily) .


A) H
B) Li
C) C
D) F
E) Ne

F) B) and D)
G) C) and D)

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Which of the following sublevels is filled last? 3d, 4s, 4p, 4d, 5s


A) 3 d
B) 4 s
C) 4 p
D) 4 d
E) 5 s

F) B) and E)
G) C) and D)

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Which of the following elements has the smallest atomic radius?


A) Li
B) Ne
C) Rb
D) Sr
E) Xe

F) A) and B)
G) A) and D)

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"Electrons added to atomic orbitals of the same energy will remain unpaired with parallel spins until the subshell is more than half-filled" is a statement of


A) the aufbau principle.
B) Hund's rule.
C) the Pauli exclusion principle.
D) the periodic law.
E) the singularity rule.

F) A) and C)
G) None of the above

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The maximum number of electrons in an atom with the same value of n is 2n2.

A) True
B) False

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