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The normal boiling point of ether is 307.8 K. Calculate the temperature at which its vapor pressure is exactly half of that at its normal boiling point. The heat of vaporization for ether is 26.69 kJ/mol.


A) 305 K
B) 302 K
C) 295 K
D) 289 K
E) 281 K

F) A) and B)
G) A) and E)

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A metal such with a face-centered cubic lattice will have ________________ atom(s) per unit cell.


A) 1
B) 2
C) 3
D) 4
E) 10

F) D) and E)
G) A) and C)

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Which of the following should have the lowest boiling point?


A) C5H12
B) C6H14
C) C8H18
D) C10H22
E) C12H26

F) A) and D)
G) None of the above

Correct Answer

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Which of the following pairs is arranged with the particle of higher polarizability listed first?


A) CCl4, CI4
B) H2O, H2Se
C) C6H14, C4H10
D) NH3, NF3
E) None of these choices are correct.

F) A) and C)
G) B) and C)

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If the solid form of a pure substance is denser than its liquid form, an increase in pressure will cause the melting point to decrease.

A) True
B) False

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In which of the following compounds will the molecules not form hydrogen bonds with each other?


A) In which of the following compounds will the molecules not form hydrogen bonds with each other? A)    B)    C)    D)    E)
B) In which of the following compounds will the molecules not form hydrogen bonds with each other? A)    B)    C)    D)    E)
C) In which of the following compounds will the molecules not form hydrogen bonds with each other? A)    B)    C)    D)    E)
D) In which of the following compounds will the molecules not form hydrogen bonds with each other? A)    B)    C)    D)    E)
E) In which of the following compounds will the molecules not form hydrogen bonds with each other? A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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The phase diagram of a substance can be used to obtain the vapor pressure of that substance at a given temperature.

A) True
B) False

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The energy of a hydrogen bond is greater than that of a typical covalent bond.

A) True
B) False

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Smectic liquid crystals are more highly ordered than either nematic or cholesteric liquid crystals.

A) True
B) False

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A liquid may be made to boil at room temperature, simply by lowering the pressure.

A) True
B) False

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What adjective best describes the solid compound IF7?


A) metallic
B) amorphous
C) covalent network
D) molecular
E) ionic

F) C) and E)
G) A) and B)

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The strongest intermolecular interactions between pentane (C5H12) molecules arise from


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) ion-dipole interactions.
E) carbon-carbon bonds.

F) All of the above
G) C) and D)

Correct Answer

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Some of the information obtained from the heating or cooling curve of a substance can also be found on a phase diagram of that substance.

A) True
B) False

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Neon atoms are attracted to each other by


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) intramolecular forces.

F) C) and D)
G) A) and B)

Correct Answer

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The strongest intermolecular interactions between hydrogen sulfide (H2S) molecules arise from


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) ion-dipole interactions.
E) disulfide linkages.

F) None of the above
G) C) and D)

Correct Answer

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In a transistor, the current through one semiconductor junction controls the current through a neighboring junction.

A) True
B) False

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Pentane, C5H12, boils at 35°C. Which of the following is true about kinetic energy, Ek, and potential energy, Ep, when liquid pentane at 35°C is compared with pentane vapor at 35°C?


A) Ek(g) < Ek(l) ; Ep(g) ≈ Ep(l)
B) Ek(g) > Ek(l) ; Ep(g) ≈ Ep(l)
C) Ep(g) < Ep(l) ; Ek(g) ≈ Ek(l)
D) Ep(g) > Ep(l) ; Ek(g) ≈ Ek(l)
E) Ep(g) ≈ Ep(l) ; Ek(g) ≈ Ek(l)

F) D) and E)
G) None of the above

Correct Answer

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Which one of the following substances will have hydrogen bonds between molecules?


A) (CH3) 3N
B) CH3-O-CH3
C) CH3CH2-OH
D) CH3CH2-F
E) HI

F) A) and C)
G) B) and D)

Correct Answer

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Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?


A) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?  A)    B)    C)    D)    E)  None of the answers are correct
B) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?  A)    B)    C)    D)    E)  None of the answers are correct
C) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?  A)    B)    C)    D)    E)  None of the answers are correct
D) Which of the following pairs of substances is arranged so that the one with higher viscosity is listed first?  A)    B)    C)    D)    E)  None of the answers are correct
E) None of the answers are correct

F) A) and B)
G) C) and D)

Correct Answer

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Only molecules that do not have dipole moments can experience dispersion forces.

A) True
B) False

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