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A solution is prepared by adding 0.10 mol of potassium chloride, KCl, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) One needs to know the temperature before any of these predictions can be made.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) B) and E)
G) B) and D)

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If a strong acid such as HCl is diluted sufficiently with water, the pH will be higher than 7.

A) True
B) False

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Which of the following is the strongest base?


A) CH3NH2
B) NaNO3
C) B(OH) 3
D) Al(OH) 3
E) LiOH

F) A) and B)
G) A) and C)

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What is the value of Kb for the cyanide anion, CN-? Ka(HCN) = 6.2 × 10-10


A) 1.6 × 10-4
B) 1.6 × 10-5
C) 3.8 × 10-4
D) 3.8 × 10-5
E) 6.2 × 104

F) C) and D)
G) D) and E)

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What is the pOH of a 0.0085 M KOH solution?


A) 2.07
B) 4.77
C) 9.23
D) 11.93
E) None of these choices are correct.

F) C) and E)
G) All of the above

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What is the pH of a 0.050 M HBr solution?


A) 0.89
B) 1.12
C) 1.30
D) 3.00
E) None of these choices are correct.

F) B) and E)
G) B) and D)

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Which one of the following substances will give an aqueous solution of pH < 7?


A) KI
B) NH4Br
C) Na2CO3
D) CH3COONa
E) CH3OH

F) A) and D)
G) A) and C)

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What is the pH of a 0.010 M triethanolammonium chloride, (HOC2H2) 3NHCl, solution? Kb, ((HOC2H2) 3N) = 5.9 × 10-7


A) 2.75
B) 4.89
C) 9.11
D) 11.25
E) None of these choices are correct.

F) B) and D)
G) A) and B)

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Ammonium chloride is used as an electrolyte in dry cells. Which of the following statements about a 0.10 M solution of NH4Cl, is correct?


A) The solution is weakly basic.
B) The solution is strongly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) B) and C)
G) A) and D)

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A solution of sodium acetate (CH3COONa) in water is weakly basic.

A) True
B) False

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Which of the following aqueous systems has the highest pH?


A) 0.1 M HA, pKa = 11.89
B) 0.1 M HMO, pKa = 8.23
C) 0.1 M HA, pKa = 4.55
D) 0.1 M HBO, pKa = 2.43
E) pure water

F) None of the above
G) A) and D)

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Select the strongest acid from the following list.


A) HBrO
B) HBrO2
C) HClO2
D) HClO3
E) HIO

F) B) and D)
G) A) and D)

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What is the pH of a 0.00200 M HClO4 solution?


A) 0.995
B) 1.378
C) 2.699
D) 6.215
E) None of these choices are correct.

F) C) and E)
G) C) and D)

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A solution is prepared by adding 0.10 mol of lithium nitrate, LiNO3, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is weakly acidic.
D) The solution is strongly acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) B) and D)
G) B) and C)

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A 0.15 M solution of chloroacetic acid has a pH of 1.86. What is the value of Ka for this acid?


A) 7.2 × 101
B) 0.16
C) 0.099
D) 0.0014
E) 0.00027

F) All of the above
G) C) and D)

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Butyric acid is responsible for the odor in rancid butter. A solution of 0.25 M butyric acid has a pH of 2.71. What is the Ka for the acid?


A) 0.36
B) 2.4 × 10-2
C) 7.8 × 10-3
D) 1.5 × 10-5
E) None of these choices are correct.

F) All of the above
G) C) and D)

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A 0.050 M solution of the weak acid HA has [H3O+] = 3.77 × 10-4 M. What is the Ka for the acid?


A) 7.5 × 10-3 M
B) 2.8 × 10-6 M
C) 7.0 × 10-7 M
D) 7.0 × 10-8 M
E) 2.6 × 10-11 M

F) A) and C)
G) A) and D)

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A solution is prepared by adding 0.10 mol of sodium fluoride, NaF, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentrations of fluoride ions and sodium ions will be identical.
E) The concentration of fluoride ions will be greater than the concentration of sodium ions.

F) B) and E)
G) D) and E)

Correct Answer

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Which of the following aqueous liquids is the most acidic?


A) 0.1 M Al(NO3) 3, Ka = 1 × 10-5
B) 0.1 M Be(NO3) 2, Ka = 4 × 10-6
C) 0.1 M Pb(NO3) 2, Ka = 3 × 10-8
D) 0.1 M Ni(NO3) 2, Ka = 1 × 10-10
E) pure water

F) B) and C)
G) C) and E)

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Which of the following aqueous liquids will have the highest pH?


A) 0.1 M CH3COOH, pKa = 4.7
B) 0.1 M CuCl2, pKa = 7.5
C) 0.1 M H3C6H5O7, pKa = 3.1
D) 0.1 M ZnCl2, pKa = 9.0
E) pure water

F) D) and E)
G) A) and D)

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