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What intermolecular force is generally considered the strongest?


A) Hydrogen bonding
B) London dispersion forces
C) Covalent bonds
D) Dipole-dipole

E) A) and B)
F) A) and C)

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Which of the following correctly matches the molecules to the names of the functional group? I. CH3OH Carboxylic acid II) CH3CO2CH3 Ester III) CH3COCH3 Ketone IV) H2CO Alcohol


A) I and II
B) III and IV
C) II and III
D) II and IV

E) B) and D)
F) B) and C)

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The indicated bond is: The indicated bond is:   A) Nucleophilic because it is electron-deficient. B) Electrophilic because it is electron-rich. C) Nucleophilic because it is electron-rich. D) Electrophilic because it is electron-deficient.


A) Nucleophilic because it is electron-deficient.
B) Electrophilic because it is electron-rich.
C) Nucleophilic because it is electron-rich.
D) Electrophilic because it is electron-deficient.

E) A) and B)
F) A) and C)

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The indicated carbon atom is: The indicated carbon atom is:   A) Electrophilic because it is electron-deficient. B) Nucleophilic because it is electron-deficient. C) Electrophilic because it is electron-rich. D) Nucleophilic because it is electron-rich.


A) Electrophilic because it is electron-deficient.
B) Nucleophilic because it is electron-deficient.
C) Electrophilic because it is electron-rich.
D) Nucleophilic because it is electron-rich.

E) C) and D)
F) A) and B)

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A

Which of the following lists the correct functional groups found in aspartame,the artificial sweetener? Which of the following lists the correct functional groups found in aspartame,the artificial sweetener?   A) Amine,aromatic,carboxylic acid,ether,ketone B) Amine,amide,aromatic,carboxylic acid,ester C) Amide,alcohol,aromatic,carboxylic acid,ether D) Amine,aromatic,carboxylic acid,ester,nitrile


A) Amine,aromatic,carboxylic acid,ether,ketone
B) Amine,amide,aromatic,carboxylic acid,ester
C) Amide,alcohol,aromatic,carboxylic acid,ether
D) Amine,aromatic,carboxylic acid,ester,nitrile

E) None of the above
F) All of the above

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B

Which of the following structures contains an alkene? Which of the following structures contains an alkene?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and B)
F) A) and C)

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Rank the following compounds in order of increasing strength of intermolecular forces,putting the molecule with the weakest intermolecular force first. Rank the following compounds in order of increasing strength of intermolecular forces,putting the molecule with the weakest intermolecular force first.   A) I < II < III B) II < I < III C) I < III < II D) II < III < I


A) I < II < III
B) II < I < III
C) I < III < II
D) II < III < I

E) C) and D)
F) None of the above

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Which of the following compounds is expected to be H2O soluble? Which of the following compounds is expected to be H<sub>2</sub>O soluble?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and B)
F) All of the above

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Consider the molecule atenolol (a β blocker used to treat hypertension) .Which of the following lists the correct functional groups present in atenolol? Consider the molecule atenolol (a β blocker used to treat hypertension) .Which of the following lists the correct functional groups present in atenolol?   A) Primary alcohol,amide,primary amine,aromatic,ether B) Secondary alcohol,amide,secondary amine,aromatic,ether C) Secondary alcohol,amide,primary amine,aromatic,ether D) Secondary alcohol,amide,secondary amine,aromatic,ester


A) Primary alcohol,amide,primary amine,aromatic,ether
B) Secondary alcohol,amide,secondary amine,aromatic,ether
C) Secondary alcohol,amide,primary amine,aromatic,ether
D) Secondary alcohol,amide,secondary amine,aromatic,ester

E) None of the above
F) A) and C)

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Rank the following compounds in order of increasing strength of intermolecular forces. Rank the following compounds in order of increasing strength of intermolecular forces.   A) I > III > IV > II B) IV > II > I > III C) IV > I > III > II D) I > IV > II > III


A) I > III > IV > II
B) IV > II > I > III
C) IV > I > III > II
D) I > IV > II > III

E) A) and B)
F) All of the above

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Which of the following structures contains a primary amine? Which of the following structures contains a primary amine?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) None of the above
F) C) and D)

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What intermolecular force is generally considered the weakest?


A) Hydrogen bonding
B) London dispersion forces
C) Dipole-dipole
D) Ion-ion

E) A) and D)
F) B) and C)

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B

Which of the following molecules are aromatic hydrocarbons? Which of the following molecules are aromatic hydrocarbons?   A) I B) II C) III D) I and III


A) I
B) II
C) III
D) I and III

E) A) and D)
F) A) and C)

Correct Answer

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The indicated bond is: The indicated bond is:   A) Nucleophilic because it is electron-deficient. B) Electrophilic because it is electron-deficient. C) Nucleophilic because it electron-rich. D) Electrophilic because it is electron-rich.


A) Nucleophilic because it is electron-deficient.
B) Electrophilic because it is electron-deficient.
C) Nucleophilic because it electron-rich.
D) Electrophilic because it is electron-rich.

E) B) and C)
F) B) and D)

Correct Answer

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Which of the following statements about vitamin C,drawn below,is true? Which of the following statements about vitamin C,drawn below,is true?   A) Vitamin C is insoluble in H<sub>2</sub>O. B) Vitamin C is soluble in H<sub>2</sub>O. C) Vitamin C is an aliphatic hydrocarbon. D) Vitamin C contains a ketone functional group.


A) Vitamin C is insoluble in H2O.
B) Vitamin C is soluble in H2O.
C) Vitamin C is an aliphatic hydrocarbon.
D) Vitamin C contains a ketone functional group.

E) A) and B)
F) All of the above

Correct Answer

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Which of the following statements best describes the relationship between the surface area of a molecule and the strength of the intermolecular forces?


A) The larger the surface area,the weaker the intermolecular forces.
B) The larger the surface area,the stronger the intermolecular forces.
C) The smaller the surface area,the stronger the intermolecular forces.
D) There is no relationship between surface area and intermolecular forces.

E) B) and D)
F) A) and B)

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List the intermolecular forces present in the following molecule: List the intermolecular forces present in the following molecule:   A) Van der Waals B) Dipole-dipole interactions C) Hydrogen bonding D) More than one of these answer choices is correct.


A) Van der Waals
B) Dipole-dipole interactions
C) Hydrogen bonding
D) More than one of these answer choices is correct.

E) C) and D)
F) A) and B)

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Which of the following statements about the solubility of organic compounds in H2O is true?


A) The non-polar part of a molecule that is not attracted to water is said to be hydrophilic.
B) The non-polar part of a molecule that is not attracted to water is said to be hydrophobic.
C) The polar part of a molecule that can that can bond hydrogen to water is said to be hydrophobic.
D) For an organic compound with one functional group that contains an O or N atom,the compound is water soluble only if it has 35 carbons.

E) A) and B)
F) A) and C)

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Which of the following compounds has the highest boiling point? Which of the following compounds has the highest boiling point?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) All of the above
F) C) and D)

Correct Answer

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Which of the following correctly matches the molecules to the names of the functional group? I. CH3NH2 Amide II) CH3SCH3 Sulfide III) CH3CONH2 Amine IV) CH3CO2CH3 Ester


A) I and II
B) II and IV
C) III and IV
D) II and III

E) B) and C)
F) A) and D)

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